Polymer modified asphalt for industrial applications

ABSTRACT

This invention provides for a method for producing polymer modified asphalt (PMA) using base asphalt (bitumen) blended with partially air blown (“puffed”) asphalt which is further modified with polymers and additives to attain desired properties for industrial applications. The partially blown or blown asphalt is oxidized to a target softening point to suit the application. In another embodiment, the base asphalt is blended with hard PEN asphalt (“Zero PEN Asphalt”) which is further modified with polymers and additives to attain desired properties for industrial applications. By using the partially oxidized asphalt or blending the base asphalt with partially oxidized asphalt or hard PEN asphalt, the amount of polymers and additives needed to achieve desired properties and performance are significantly reduced. In fact, this technique can be used to attain polymer modified asphalt having a highly desirable combination of characteristics that could not otherwise be attained using the base asphalt.

This is a continuation of U.S. patent application Ser. No. 15/726,752filed on Oct. 6, 2017, which claims the benefit of U.S. ProvisionalPatent Application Ser. No. 62/405,013, filed on Oct. 6, 2016. Theteachings of U.S. patent application Ser. No. 15/726,752 and U.S.Provisional Patent Application Ser. No. 62/405,013 are incorporatedherein by reference in their entirety.

BACKGROUND OF THE INVENTION

Asphalt, which is widely known as bitumen outside of North America,offers outstanding binding and waterproofing characteristics. Thesephysical attributes of asphalt have led to its widespread utilization inpaving, roofing, and waterproofing applications. For instance, asphaltis used in manufacturing roofing shingles because it has the ability tobind sand, aggregate, and fillers to the roofing shingle whilesimultaneously providing excellent water barrier characteristics.

Naturally occurring asphalts have been used in various applications forhundreds of years. However, today almost all of the asphalt used inindustrial applications is recovered from the refining of petroleum.Asphalt, or asphalt flux, is essentially the residue that remains aftergasoline, kerosene, diesel fuel, jet fuel, and other hydrocarbonfractions have been removed during the refining of crude oil. In otherwords, asphalt flux is the last cut from the crude oil refining process.

Industrial asphalt for utilization in manufacturing roofing shingles andother products has generally been made by employing only certain gradesof asphalt flux as a raw material. This specific type of asphalt,sometimes referred to a roofer's flux, is normally air blown to increaseits softening point and to decrease its penetration value into rangeswhich are suitable for use in manufacturing roofing products. Thisspecific type of asphalt typically has a higher penetration value andlower viscosity than the asphalt used in paving applications. However,these grades of asphalts that can be air blown into industrial asphaltsfor roofing and other applications are increasingly in short supply.These grades of asphalt are also becoming more and more expensive due tohigh demand and low supply.

In any case, to meet performance standards and product specifications,asphalt flux that is recovered from refining operations is normallytreated or processed to attain desired physical characteristics and toattain uniformity. For instance, asphalt that is employed inmanufacturing roofing products has to be treated to meet the specialrequirements demanded in roofing applications. More specifically, in theroofing industry it is important to prevent asphaltic materials fromflowing under conditions of high temperature such as those encounteredduring hot summers. In other words, the asphaltic materials used inroofing products should maintain a certain level of stiffness (hardness)at high temperatures. This increased level of stiffness is characterizedby a reduced penetration, an increased viscosity, and an increasedsoftening point.

To attain the required level of stiffness and increased softening pointthat is demanded in roofing applications the asphalt flux is typicallytreated by an air blowing process. In such air blowing techniques, airis blown through the asphalt flux for a period of about 2 to about 8hours while it is maintained at an elevated temperature which istypically within the range of 400° F. (204° C.) to 550° F. (288° C.).The air blowing process optimally results in the stiffness and thesoftening point of the asphalt flux being significantly increased. Thisis highly desirable because ASTM D 3462-96 (Standard Specification forAsphalt Shingles Made from Glass Felt and Surfaced with MineralGranules) requires roofing asphalt to have a softening point which iswithin the range of 190° F. (88° C.) to 235° F. (113° C.) and for theasphalt to exhibit a penetration at 77° F. (25° C.) of above 15 dmm (1dmm=0.1 mm). In fact, it is typically desirable for asphalt used inroofing applications to have a penetration which is within the range of15 dmm to 35 dmm in addition to a softening point which is within therange of 185° F. (85° C.) to 235° F. (113° C.).

Air blowing has been used to increase the softening point and stiffnessof asphalt since the early part of the twentieth century. For example,U.S. Pat. No. 2,179,208 describes a process wherein asphalt is air blownat a temperature of 300° F. (149° C.) to 500° F. (260° C.) in theabsence of a catalyst for a period of 1 to 30 hours after which time acatalyst is added for an additional treatment period of 20 to 300minutes at a temperature of 225° F. (107° C.) to 450° F. (232° C.). Overthe years a wide variety of chemical agents have been used as airblowing catalysts. For instance, ferric chloride, FeCl.₃ (see U.S. Pat.No. 1,782,186), phosphorous pentoxide, P₂O₅ (see U.S. Pat. No.2,450,756), aluminum chloride, AlCl₃ (see U.S. Pat. No. 2,200,914),boric acid (see U.S. Pat. No. 2,375,117), ferrous chloride, FeCl₂,phosphoric acid, H₃PO₄ (see U.S. Pat. No. 4,338,137), copper sulfateCuSO, zinc chloride ZnCl₂, phosphorous sesquesulfide, P₄S₃, phosphorouspentasulfide, P₂S₅, and phytic acid, C₆H₆O₆(H₂PO₃)₆ (see U.S. Pat. No.4,584,023) have all been identified as being useful as air blowingcatalysts.

U.S. Pat. No. 2,179,208 discloses a process for manufacturing asphaltswhich comprises the steps of air-blowing a petroleum residuum in theabsence of any added catalysts while maintaining the temperature atabout 149° C. to 260° C. (300° F. to 500° F.) and then heating thematerial at a temperature at least about 149° C. (300° F.) with a smallamount of a polymerizing catalyst. Examples of such polymerizingcatalysts include chlorosulphonic, phosphoric, fluoroboric,hydrochloric, nitric or sulfuric acids and halides as ferric chloride,aluminum bromide, chloride, iodide, halides similarly of copper, tin,zinc, antimony, arsenic, titanium, etc. hydroxides of sodium, potassium,calcium oxides, sodium carbonate, metallic sodium, nitrogen bases,ozonides and peroxides. Blowing with air can then be continued in thepresence of the polymerizing catalyst.

U.S. Pat. No. 2,287,511 discloses an asphalt manufacturing process whichinvolves heating a residuum in the presence of the following catalysts:ferric chloride, aluminum bromide, aluminum chloride, aluminum iodide;halides of copper, tin, zinc, antimony, arsenic, boron, titanium;hydroxides of sodium and potassium; calcium oxides, sodium carbonate,and metallic sodium. These catalysts are described as being present inthe asphalt composition in the absence of any injected air. However, airmay be injected prior to the addition of the above-cited polymerizingcatalysts, but no air is injected when the catalysts have been added tothe composition.

U.S. Pat. No. 4,000,000 describes a process for recyclingasphalt-aggregate compositions by heating and mixing them with a desiredamount of petroleum hydrocarbons containing at least 55% aromatics.

U.S. Pat. No. 2,370,007 reveals a process for oxidizing asphalt whichinvolves air blowing a petroleum oil in the presence of a relativelysmall amount of certain types of catalysts. These catalysts are organiccomplexes of metallic salts. Examples of organic complexes of metallicsalts that can be used include those obtained from sludges recovered intreating petroleum fractions with metallic salts, such as metallichalides, carbonates and sulfates. The sludge obtained in treating acracked gasoline with aluminum chloride is disclosed as beingparticularly suitable in accelerating the oxidation reaction and inproducing an asphalt of superior characteristics. The hydrocarbon stocksfrom which the organic complex of metallic salts may be produced aredescribed as including various hydrocarbon fractions containinghydrocarbons which are reactive with the metallic salts, such as thosecontaining olefinic hydrocarbons. Sludges obtained by treating olefinswith aluminum chloride are also described as being useful in the processof this 1943 patent. Other sludges that are identified as beingparticularly useful can be obtained in the isomerization of hydrocarbonssuch as butane, pentane and naphtha in the presence of aluminumchloride. These sludges can be obtained by the alkylation ofisoparaffins with olefins in the presence of such alkylating catalysts,such as boron trifluoride and the like.

Several patents describe the application of phosphoric mineral acids inmodifying asphalt properties. For instance, U.S. Pat. No. 2,450,756describes a process to make oxidized asphalts by air blowing petroleumhydrocarbon in the presence of a phosphorus catalyst, includingphosphorus pentoxide, phosphorus sulfide, and red phosphorus. U.S. Pat.No. 2,762,755 describes a process of air blow asphaltic material in thepresence of a small amount of phosphoric acid. U.S. Pat. No. 3,126,329discloses a method of making blown asphalt through air blowing in thepresence of a catalyst which is an anhydrous solution of 50 weightpercent to 80 weight percent phosphorus pentoxide in 50 weight percentto 20 weight percent phosphoric acid having the general formulaH_(m)R_(n)PO₄.

In general, the air blowing techniques described in the prior art sharethe common characteristic of both increasing the softening point anddecreasing the penetration value of the asphalt flux being treated. Inother words, as the asphalt flux is air blown, its softening pointincreases and its penetration value decreases over the duration of theair blowing procedure. It has been the conventional practice to air blowasphalt flux for a period of time that is sufficient to attain thedesired softening point and penetration value. However, in the case ofsome asphalt fluxes, air blowing to the desired softening point usingconventional procedures results in a penetration value which is too lowto be suitable for utilization in roofing applications. These asphaltfluxes are called “hard asphalt fluxes”. In other words, hard asphaltfluxes cannot be air blown using conventional procedures to a pointwhere both the required softening point and penetration values areattained. Accordingly, there is a need for techniques that can be usedto air blow hard asphalt flux to both a softening point which is withinthe range of 185° F. (85° C.) to 250° F. (121° C.) and a penetrationvalue at 77° F. (25° C.) of above 15 dmm.

U.S. Pat. Nos. 4,659,389 and 4,544,411 disclose the preparation ofsatisfactory asphaltic roofing fluxes from otherwise unsatisfactoryfluxes which involves the addition of asphaltenes, and saturates inquantities which satisfy certain specified conditions. Air oxidation ofthe flux is described in these patents as being surprisingly acceleratedby the addition of highly branched saturates, especially in the presenceof a carbonate oxidation catalyst. Some examples of saturates which aredescribed in these patents as being useful in the method describedtherein include slack wax, petrolatums, hydrocarbyl species, andmixtures thereof.

U.S. Pat. No. 7,901,563 discloses a method for preparing an industrialasphalt comprising (1) heating an asphalt flux to a temperature which iswithin the range of about 400° F. (204° C.) to 550° F. (288° C.) toproduce a hot asphalt flux, (2) sparging an oxygen containing gasthrough the hot asphalt flux for a period of time which is sufficient toincrease the softening point of the asphalt flux to a value of at least100° F. (38° C.), to produce an underblown asphalt composition; and (3)mixing a sufficient amount of a polyphosphoric acid throughout theunderblown asphalt composition while the underblown asphalt compositionis maintained at a temperature which is within the range of 200° F. (93°C.) to 550° F. (288° C.) to attain a softening point which is within therange of 185° F. (85° C.) to 250° F. (121° C.) and a penetration valueof at least 15 dmm at 77° F. (25° C.) to produce the industrial asphalt.The techniques disclosed in this patent is useful in that it can be usedto increase the softening point of hard asphalt flux to a commerciallydesirable level while maintaining the penetration value of the asphaltabove 15 dmm at 77° F. (25° C.). Accordingly, this technique can be usedto produce industrial asphalt having a desirable softening point andpenetration value using hard asphalt flux as the starting material.

Asphalts have been modified with waxes to produce a variety of roofingand industrial products. For example, U.S. Pat. No. 4,382,989 disclosesa roofing asphalt formulation containing oxidized coating grade asphalt,oxidized polyethylene and optionally saturant asphalt and filler. In oneembodiment, the asphalt is oxidized to any degree, then unoxidizedpolyethylene is added, and then the oxidation process is continued toproduce the roofing asphalt formulation. In a later improvement U.S.Pat. No. 4,497,921 discloses the addition of sulfur to stabilize themix. U.S. Pat. No. 4,554,023 claims a method of making a roofing shingleasphalt by blending bis-stearoylamide wax into asphalt, including blownasphalt with the benefit of lowering the viscosity of the asphaltproduct being reported.

U.S. Pat. No. 7,317,045 reveals a modified bitumen composition forroofing application comprising: a polymer modifier consistingessentially of polyethylene; and asphalt, wherein the polyethyleneconsists of a mixture of high density polyethylene and low densitypolyethylene in a ratio ranging from about 4:1 to 1:4 LDPE to HDPE byweight, wherein the polyethlene is linear. The polyethylene can have aweight average molecular weight between about 1,000 and 25,000, a meltflow index value between about 5 and 50, and can be of a low density ofless than 0.95 g/cm³.

U.S. Pat. No. 7,857,904 reveals a process of producing a roofing shinglecoating asphalt from an asphalt feedstock includes the following steps.Wax and blowing catalyst are added to the asphalt feedstock. Then theasphalt feedstock is blown to produce the coating asphalt. The coatingasphalt has a softening point within a range of from about 190° F. (88°C.) to about 235° F. (113° C.) and has a penetration of at least about15 dmm at 77° F. (25° C.).

U.S. Pat. No. 7,951,239 discloses a method of producing a roofingshingle coating asphalt from a non-coating grade asphalt feedstockincludes the following steps. The non-coating grade asphalt feedstock ispartially blown to lower its penetration to a first penetration that iswithin or close to a target penetration range of the coating asphalt,and to raise its softening point to a first softening point that islower than a target softening point range of the coating asphalt. Then,a wax is added to the partially blown non-coating grade asphalt tofurther raise its softening point to a second softening point that iswithin the target softening point range to produce the coating asphalt.

U.S. Pat. No. 8,753,442 discloses method of producing a roofing shinglecoating asphalt from a non-coating grade asphalt feedstock includes thefollowing steps. The non-coating grade asphalt feedstock is partiallyblown to lower its penetration to a first penetration that is within orclose to a target penetration range of the coating asphalt, and to raiseits softening point to a first softening point that is lower than atarget softening point range of the coating asphalt. A wax is added tothe partially blown non-coating grade asphalt to further raise itssoftening point to a second softening point that is within the targetsoftening point range to produce the coating asphalt. The wax may alsobe added during the blowing process. Resulting roofing coating asphaltcompositions may comprise a paving grade asphalt and a wax, and yetstill has desirable penetration, softening point and viscosity.

U.S. Pat. Nos. 8,808,445 and 8,926,742 describe a process for preparingan asphalt-coated crumb rubber composition that meets the specificationset forth in ASTM D80-02 or deviations thereof which may be establishedby the specifying agency from time to time. This process generallycomprises obtaining asphalt of different penetration grades, combiningthe asphalt of each grade with preselected chemicals to form separatepremixed components, blending the premixed components together underpredetermined conditions to form, upon curing, an asphalt-coated crumbrubber composition that meets certain physical requirements forasphalt-rubber binder (ARB), such as those set forth in ASTM D8-02.Advantageously, the resulting asphalt-coated crumb rubber compositionnot only meets the physical requirements of ARB used in road paving butalso has improved dispersion of the rubber, such as dispersion of therubber in an oil-in-water emulsion of an asphalt.

U.S. Pat. No. 8,901,211 reveals a method for preparing an industrialasphalt comprising sparging an oxygen containing gas through an asphaltflux in the presence of 0.25 weight percent to about 12 weight percentof a highly saturated rubbery polymer at a temperature within the rangeof about 400° F. to about 550° F. for a period of time which issufficient to increase the softening point of the asphalt flux to avalue which is within the range of 185° F. to 250° F. and a penetrationvalue of at least 15 dmm to produce the industrial asphalt. The highlysaturated rubbery polymer can be a styrene-ethylene/butylene-styreneblock copolymer rubber or a highly saturatedstyrene-ethylene/propylene-styrene block copolymer rubber.

SUMMARY OF THE INVENTION

This invention provides for a method for producing polymer modifiedasphalt (PMA) using base asphalt (bitumen) blended with partially airblown (“puffed”) asphalt which is further modified with polymers andadditives to attain desired properties for industrial applications. Thepartially blown or blown asphalt is oxidized to a target softening pointto suit the application. In another embodiment of the invention, thebase asphalt is blended with hard PEN asphalt (“Zero PEN Asphalt”) whichis further modified with polymers and additives to attain desiredproperties for industrial applications. By using the partially oxidizedasphalt or blending the base asphalt with partially oxidized asphalt orhard PEN asphalt, the amount of polymers and additives needed to achievedesired properties and performance are significantly reduced. In fact,this technique can be used to attain polymer modified asphalt having ahighly desirable combination of characteristics that could not otherwisebe attained using the base asphalt.

This technique of blending partially air blown asphalt and/or hard PENasphalt with base asphalt allows for the use of asphalt types andasphalt streams that would not otherwise be considered for use in makingindustrial asphalt having desired characteristics. In other words, thetechnique of this invention makes it possible to employ asphalt streamsthat would not otherwise be physically, mechanically or chemicallysuitable for use. In another embodiment of the invention, partiallyoxidized asphalt or blended asphalts are used in combination withpolymers and additives, such as waxes and/or plasticizers to producepolymer modified asphalts of desired properties and performance. Byutilizing asphalts that are partially blown or not blown at all, blowloss and emissions are significantly reduced thus providing a moreenvironmentally friendly method of producing asphalt. This method allowsfor the production of industrial asphalt with reduced thermal history ascompared to asphalt made with conventional air blowing processes. Thesoftening points for the partially oxidized asphalts used in accordancewith this invention can be adjusted to compensate for variations in thecharacteristic and quality of base asphalt streams. Accordingly, thetechnique of this invention provides a more forgiving process fortreating base asphalt than is possible by practicing techniques of theprior art.

The technique of this invention allows for the use of base asphaltsinclude paving grades, flux grades, PEN grades, viscosity grade, agedresidue grades and the likes in making high quality industrial asphaltwhich is suitable for use in manufacturing asphalt roofing shingles andother value added products. The hard PEN asphalts that can be usedinclude vacuum tower bottom asphalt, propane distilled asphalt, ROSEasphalt, oxidized or blown asphalt and the like. The polymers that canbe employed in modifying the asphalt compositions of this inventioninclude thermoplastic elastomers, more preferably styrenic blockcopolymers, polyolefins, acrylate copolymers, maleated polymers/resins,ground tire rubber, and the like. The waxes that can be included in theasphalt compositions of this invention include natural and syntheticwaxes. The plasticizers that can be utilized in the asphalt compositionsof this invention include aromatic oils, naphthenic oils, triglycerideoils (vegetable oils) and other forms of natural and synthetic oils.

The appropriate components ratios needed to produce the desired PMA maybe batched together or consecutively added, if desired, and can be mixedusing a high shear or low shear mill at 200° F. top 450° F. to obtain ahomogeneous blend. The properties of these asphalt blend compositionscan be tested using various analytical methods and ASTM Methods toestablish fitness for use in particular applications such in coatingsfor roofing shingles, modified asphalt based adhesives, paving and otherapplications.

The present invention more specifically discloses a method for producingan industrial asphalt composition which comprises blending a partiallyblown asphalt or a hard PEN asphalt into an asphalt base which isselected from the group consisting of paving grade asphalts, flux gradeasphalts, PEN grade asphalts, viscosity grade asphalts, and aged residuegrade asphalts.

This invention also discloses an asphalt composition which is comprisedof a base asphalt, a partially blown asphalt, a polymer modifier, and atleast one wax.

The subject invention further reveals an asphalt composition which iscomprised of a base asphalt, a hard PEN asphalt, a polymer modifier, andat least one wax.

DETAILED DESCRIPTION OF THE INVENTION

In accordance with this invention, partially oxidized or partially blownasphalt is further modified using polymers and/or additives. By usingthe partially oxidized asphalt or blending the base asphalt withpartially oxidized asphalt or hard PEN asphalt, the amount of polymersand additives needed to achieve desired properties and performance aresignificantly reduced. Targeting various softening points for thepartially oxidized asphalt which may or may not be blended with baseasphalts (at various ratios) can be used to mitigate base asphaltquality variation. This technique of blending partially air blownasphalt and/or hard PEN asphalt with base asphalt broadens the types ofasphalt available for use which would not otherwise be physically,mechanically or chemically suitable for use.

In the practice of this invention partially oxidized or partially blownasphalt and the base asphalt are blended and modified using polymersand/or additives. The partially blown asphalt has softening point whichis within the range of 120° F. to 230° F., a penetration at 77° F. of 5dmm to 30 dmm and a rotational viscosity of 120-450 cP at 400° F. Morepreferably the partially blown asphalt has softening point which iswithin the range of 140° F. to 190° F., a penetration at 77° F. which iswithin the range of 8 dmm to 16 dmm and a rotational viscosity which iswithin the range of 120 cP to 400 cP at 400° F.

Hard PEN grade asphalts (“Zero PEN asphalts”) from refineries blendedwith base asphalts and modified with polymers and/or additives can beutilized in the practice of this invention. The hard PEN asphaltutilized in the process of this invention will have a softening pointwhich is within the range of 140° F. to 240° F., a penetration at 77° F.of 0.5 dmm to 15 dmm and rotational viscosity which is within the rangeof 25 cP to 450 cP at 400° F. The hard PEN asphalt will preferable havea softening point which is within the range of 150° F. to 210° F., apenetration value at 77° F. which is within the range of 0.2 dmm to 10dmm, and a rotational viscosity which is within the range of 140 cP to350 cP at 400° F.

Partially blown asphalt and/or hard PEN asphalt and base asphalt areblended together and can be further modified using asphalt modificationpolymers and/or additional additives. The partially oxidized asphaltconstitutes 5 weight percent to 95 weight percent of the PMA and morepreferably 20 weight percent to 90 weight percent of the PMA. Asphaltblends made with hard PEN asphalt will typically contain from 5 weightpercent to 50 weight percent of the hard PEN asphalt and 50 weightpercent to 95 weight percent of the base asphalt. The asphalt blend willpreferably contain from 5 weight percent to 40 weight percent of thehard PEN asphalt.

The polymers that can be used for asphalt modification in accordancewith this invention include block copolymers, such as SBS, SEBS,copolymers of functionalized reactive elastomers (RET) or glycidylacrylate copolymers of methyl, ethyl, butyl acrylates, and polyolefinhomo-polymers and copolymers such as polypropylene,polypropylene/ethylene copolymers and the likes. Partially blown asphaltcan be blended with a block copolymer such as SEBS or SBS and a wax toyield a PMA suitable for manufacturing roofing products, paving andother industrial applications. The hard PEN asphalt can also be blendedwith base asphalt which is further modified with a block copolymer suchas SEBS or SBS and wax to yield PMA suitable for paving, manufacturingroofing products and other industrial applications. The partially blownasphalt or hard PEN asphalt can also be blended with base asphalt whichis further modified with polyolefins, crumb rubber, or ground tirerubber and a wax to yield PMA suitable for manufacturing roofingproducts, road paving and other industrial applications.

In some cases, cross linking agents and co-agents may be used to improvepolymer network and dispersion in the PMA. The wax used in suchapplications can be natural or synthetic and have a softening pointwhich is within the range of 200° F. to 330° F., a penetration value at77° F. which is within the range of 0.5 dmm to 15 dmm and a rotationalviscosity of which is within the range of 2 cP to 100 cP at 400° F. andCOC flash point of greater than 400° F. The wax will more preferablyhave a softening point which is within the range of 200° F. to 350° F.,a penetration at 77° F. which is within the range of 0.5 dmm to 10 dmmand rotational viscosity which is within the range of 2 cP to 150 cP at400° F. and a COC flash point of greater than 475° F.

The ground tire rubber that can be employed in the practice of thisinvention will typically have a particle size which is within the rangeof 80 to 300 mesh and will more preferably have a mesh size which iswithin the range of 140 to 200. The plasticizers that can be utilized inthe practice of this invention include aromatic oils, naphthenic oils,triglyceride oils, vegetable oils, and other forms of natural andsynthetic oils.

Where the polymer modified asphalt (PMA) has softening point which iswithin the range of 130° F. to 260° F., a penetration at 77° F. which iswithin the range of 12 dmm to 40 dmm, and a rotational viscosity whichis within the range of 90 cP to 700 cP at 400° F. More preferably themodified asphalt will have a softening point which is within the rangeof 200° F. to 250° F., a penetration at 77° F. of 15 dmm to 32 dmm, androtational viscosity which is within the range of 100 cP to 500 cP at400° F.

The industrial asphalt produced can be used in making roofing productsand other industrial products using standard procedures. For instance,the industrial asphalt can be blended with fillers, stabilizers (likelimestone, stonedust, sand, granule, etc.), polymers, recycled tirerubber, recycled engine oil residue, recycled plastics, softeners,antifungal agents, biocides (algae inhibiting agents), and otheradditives. For instance, aggregate and/or fillers can be added to thePMA for the manufacture of building materials, roofing materials(shingles, cap sheets, rolls base sheets and the like), paving and otherindustrial applications. By utilizing asphalts that are partially blownor not blown at all, blow loss and emissions are significantly reducedthus providing a more environmentally friendly method of producingasphaltic coating.

This invention is illustrated by the following examples that are merelyfor the purpose of illustration and are not to be regarded as limitingthe scope of the invention or the manner in which it can be practiced.Unless specifically indicated otherwise, parts and percentages are givenby weight.

EXAMPLES

A series of blends were made in accordance with this invention andblends were also made in accordance with the prior art for comparativepurposes. These blends were made with various paving grade asphaltswhich could not be processed using conventional techniques intoindustrial asphalt which would be useful in roofing applications. Asummary of these compositions and their properties is reported in thefollowing tables.

TABLE 1 Base Asphalt Blown to Partially Roofing Soft- PEN Base HardBlown coating Poly- SE- Plasti- ening Viscosity at Block Exam- AsphaltPEN Asphalt Softening RET GTR olefin SBS BS cizer Wax Point at 400° 77°F. # ple % % % Point Target % % % % % % % % (° F.) F. (cP) (dmm) 1 ABase 0.0 0.0 100.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 212.3 494 9.6 Asphalt A10.0 0.0 91.0 0.0 0.0 0.0 0.0 0.0 4.0 4.0 1.0 209 309 17.5 A1-1 91.0 0.00.0 0.0 0.0 0.0 0.0 0.0 4.0 4.0 1.0 140 97 53.0 A1-2 87.0 0.0 0.0 0.00.0 0.0 0.0 0.0 8.0 4.0 1.0 200 215 40.3 A2 0.0 0.0 91.0 0.0 0.0 0.0 0.00.0 4.0 4.0 1.0 207 318 17.3 A2-1 91.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 4.04.0 1.0 178 99 61.3 A2-2 87.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 8.0 4.0 1.0224 221 52.0 2 B Base 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 209 39511.0 Asphalt B1 74.0 20.0 0.0 100.0 0.0 0.0 0.0 0.0 4.5 0.0 1.5 214 20617.3 B1-1 94.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 4.5 0.0 1.5 202 124 37.0 B1-290.5 0.0 0.0 0.0 0.0 0.0 0.0 0.0 8.0 0.0 1.5 227 367 28.3 B2 74.0 20.00.0 0.0 0.0 0.0 0.0 0.0 4.5 0.0 1.5 211 185 22.0 B2-1 94.0 0.0 0.0 0.00.0 0.0 0.0 0.0 4.5 0.0 1.5 202 124 37.0 B2-2 90.5 0.0 0.0 0.0 0.0 0.00.0 0.0 8.0 0.0 1.5 227 367 28.3 3 C Base 0.0 0.0 100.0 0.0 0.0 0.0 0.00.0 0.0 0.0 209 395 11.0 Asphalt C1 75.5 20.0 0.0 0.0 2.0 0.0 0.0 0.50.0 0.0 2.0 245 108 26.0 C1-1 95.5 0.0 0.0 0.0 2.0 0.0 0.0 0.5 0.0 0.02.0 215 54 49.3 C1-2 93.5 0.0 0.0 0.0 4.0 0.0 0.0 0.5 0.0 0.0 2.0 233115 44.0 C2 75.5 20.0 0.0 0.0 2.0 0.0 0.0 0.5 0.0 0.0 2.0 232 120 31.0C2-1 95.5 0.0 0.0 0.0 2.0 0.0 0.0 0.5 0.0 0.0 2.0 213 83 40.0 C2-2 92.00.0 0.0 0.0 2.0 0.0 0.0 4.0 0.0 0.0 2.0 239 160 34.0 D1 75.5 0.0 20.00.0 2.0 0.0 0.0 0.5 0.0 0.0 2.0 253 136 27.0 D1-1 95.5 0.0 0.0 0.0 2.00.0 0.0 0.5 0.0 0.0 2.0 213 83 40.0 D1-2 92.0 0.0 0.0 0.0 2.0 0.0 0.04.0 0.0 0.0 2.0 239 160 34.0 D2 75.5 0.0 20.0 0.0 2.0 0.0 0.0 0.5 0.00.0 2.0 223 118 37.0 D1-1 95.5 0.0 0.0 0.0 2.0 0.0 0.0 0.5 0.0 0.0 2.0220 95 34.0 D1-2 92.0 0.0 0.0 0.0 2.0 0.0 0.0 4.0 0.0 0.0 2.0 249 12338.2 4 E Base 0.0 0.0 100.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 208 391 5.0Asphalt E1 73 20.0 0.0 0.0 2.0 0.0 0.0 3.0 0.0 0.0 2.0 238 222 24.7 E1-193 0.0 0.0 0.0 2.0 0.0 0.0 3.0 0.0 0.0 2.0 223 144 30.0 E1-2 91.5 0.00.0 0.0 2.0 0.0 0.0 3.0 0.0 0.0 2.0 231 217 27.0 E2 73 20.0 0.0 0.0 2.00.0 0.0 3.0 0.0 0.0 2.0 232 154 28.3 E2-1 93 0.0 0.0 0.0 2.0 0.0 0.0 3.00.0 0.0 2.0 219 125 38.0 E2-2 91.5 0.0 0.0 0.0 2.0 0.0 0.0 3.0 0.0 0.02.0 252 196 32.0 5 F Base 0.0 0.0 100.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 209230 11.0 Asphalt F1 73 30.0 0.0 0.0 0.0 2.5 3.0 0.0 0.0 0.0 1.5 219 23629.0 F1-1 93 0.0 0.0 0.0 0.0 2.5 3.0 0.0 0.0 0.0 1.5 192 104 47.3 F1-291.5 0.0 0.0 0.0 0.0 2.5 4.5 0.0 0.0 0.0 1.5 211 172 42.3 F2 73 30.0 0.00.0 0.0 2.5 3.0 0.0 0.0 0.0 1.5 201 202 22.7 F2-1 93 0.0 0.0 0.0 0.0 2.53.0 0.0 0.0 0.0 1.5 159 122 33.5 F2-2 91.5 0.0 0.0 0.0 0.0 2.5 4.5 0.00.0 0.0 1.5 207 238 33.0 6 G Base 0.0 100.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0212 494 9.6 Asphalt G1 43 0.0 50.0 0.0 0.0 2.5 3.0 0.0 0.0 0.0 1.5 238279 18.3 G1-1 93 0.0 0.0 0.0 0.0 2.5 3.0 0.0 0.0 0.0 1.5 202 139 37.3G1-2 91.5 0.0 0.0 0.0 0.0 2.5 4.5 0.0 0.0 0.0 1.5 248 598 32.0

TABLE 2 % Softening Viscosity Block Base Partially % Poly- % Point at400° F. PEN at # Asphalt Blown SBS Butadiene Resin (° F.) (cP) 77° F.(dmm) 7 H1 No 0.00 0.00 0.00 132 31 33 H1-1 No 6.50 0.00 4.00 237 310 178 I1 Yes 0.00 0.00 0.00 210 209 12.3 I1-2 Yes 0.00 6.00 0.00 225 263 169 J1 Yes 0.00 0.00 178 144 13 J1-2 Yes 0.00 8.50 0.00 211 193 18 10 K1Yes 0.00 0.00 0.00 184 143 13 K-2 Yes 0.00 8.50 0.00 221 190 16

While certain representative embodiments and details have been shown forthe purpose of illustrating the subject invention, it will be apparentto those skilled in this art that various changes and modifications canbe made therein without departing from the scope of the subjectinvention.

What is claimed is:
 1. An industrial asphalt composition which iscomprised of a base asphalt, a partially blown asphalt, a polymermodifier, and at least one wax, wherein the base asphalt is not airblown, wherein the base asphalt is asphalt flux, wherein the partiallyblown asphalt is asphalt flux, and wherein the industrial asphaltcomposition has softening point which is within the range of 120° F. to260° F., a penetration at 77° F. which is within the range of 12 dmm to40 dmm, and a rotational viscosity which is within the range of 90 cP to700 cP at 400° F.
 2. The industrial asphalt composition of claim 1wherein the partially blown asphalt has a softening point which iswithin the range of 120° F. to 230° F., wherein the partially blownasphalt has a penetration value which is within the range of 5 dmm to 30dmm at 77° F., wherein the partially blown asphalt has a rotationalviscosity which is within the range of 120 cP to 450 cP at 400° F. 3.The industrial asphalt composition of claim 1 wherein the industrialasphalt composition includes 5 weight percent to 95 weight percent ofthe partially blown asphalt and from 5 weight percent to 95 weightpercent of the base asphalt.
 4. The industrial asphalt composition ofclaim 1 wherein the base asphalt is selected from the group consistingof paving grade asphalts, flux grade asphalts, PEN grade asphalts,viscosity grade asphalts, and aged residue grade asphalts.
 5. Theindustrial asphalt composition of claim 1 wherein the polymer modifieris present at a level which is within the range of 0.5 weight percent to12 weight percent, and wherein the wax is present at a level which iswithin the range of 0.5 weight percent to 5 weight percent.
 6. Theindustrial asphalt composition of claim 1 wherein the polymer modifieris selected from the group consisting of SBS, SEBS, copolymers offunctionalized reactive elastomers (RET) or glycidyl acrylate copolymersof methyl, ethyl, butyl acrylates, and polyolefin homo-polymers andcopolymers.
 7. The industrial asphalt composition of claim 1 wherein thewax has a softening point which is within the range of 200° F. to 330°F., a penetration value at 77° F. which is within the range of 0.5 dmmto 15 dmm, and a rotational viscosity which is within the range of 2 cPto 100 cP at 400° F., and COC flash point of greater than 400° F.
 8. Anindustrial asphalt composition which is comprised of a base asphalt, ahard PEN asphalt, a polymer modifier, and at least one wax, wherein thebase asphalt is asphalt flux, wherein the hard PEN asphalt is asphaltflux, wherein the hard PEN asphalt has a penetration value which iswithin the range of 0.2 dmm to 15 dmm at 77°, wherein the industrialasphalt composition has softening point which is within the range of120° F. to 260° F., a penetration at 77° F. which is within the range of12 dmm to 40 dmm, and a rotational viscosity which is within the rangeof 90 cP to 700 cP at 400° F.
 9. The industrial asphalt composition ofclaim 8 wherein the hard PEN asphalt has a softening point which iswithin the range of 140° F. to 240° F., wherein the hard PEN asphalt hasa penetration value which is within the range of 0.2 dmm to 10 dmm at77° F., and wherein the hard PEN asphalt has a rotational viscositywhich is within the range of 25 cP to 450 cP at 400° F.
 10. Theindustrial asphalt composition of claim 8 wherein the industrial asphaltcomposition includes 5 weight percent to 95 weight percent of the hardPEN asphalt and from 5 weight percent to 95 weight percent of the baseasphalt.
 11. The industrial asphalt composition of claim 8 wherein thebase asphalt is selected from the group consisting of paving gradeasphalts, flux grade asphalts, PEN grade asphalts, viscosity gradeasphalts, and aged residue grade asphalts.
 12. The industrial asphaltcomposition of claim 8 wherein the polymer modifier is present at alevel which is within the range of 0.5 weight percent to 12 weightpercent, and wherein the wax is present at a level which is within therange of 0.5 weight percent to 5 weight percent.
 13. The industrialasphalt composition of claim 8 wherein the polymer modifier is selectedfrom the group consisting of SBS, SEBS, copolymers of functionalizedreactive elastomers (RET) or glycidyl acrylate copolymers of methyl,ethyl, butyl acrylates, and polyolefin homo-polymers and copolymers. 14.The industrial asphalt composition of claim 8 wherein the wax has asoftening point which is within the range of 200° F. to 330° F., apenetration value at 77° F. which is within the range of 0.5 dmm to 15dmm, and a rotational viscosity which is within the range of 2 cP to 100cP at 400° F., and COC flash point of greater than 400° F.
 15. Theindustrial asphalt composition of claim 8 wherein the industrial asphaltcomposition has softening point which is within the range of 130° F. to260° F., a penetration at 77° F. which is within the range of 12 dmm to40 dmm, and a rotational viscosity which is within the range of 90 cP to700 cP at 400° F.
 16. A method for producing an industrial asphaltcomposition which comprises blending a partially blown asphalt or a hardPEN asphalt into an asphalt base which is selected from the groupconsisting of paving grade asphalts, flux grade asphalts, PEN gradeasphalts, viscosity grade asphalts, and aged residue grade asphalts,wherein the asphalt base is not air blown, wherein the base asphalt isasphalt flux, wherein the partially blown asphalt or hard PEN asphalt isasphalt flux, and wherein the industrial asphalt composition hassoftening point which is within the range of 120° F. to 260° F., apenetration at 77° F. which is within the range of 12 dmm to 40 dmm, anda rotational viscosity which is within the range of 90 cP to 700 cP at400° F.
 17. The method of claim 16 wherein partially blown asphalt isblended into the asphalt base, wherein the partially blown asphalt has asoftening point which is within the range of 120° F. to 230° F., whereinthe partially blown asphalt has a penetration value which is within therange of 5 dmm to 30 dmm at 77° F., and wherein the partially blownasphalt has a rotational viscosity which is within the range of 120 cPto 450 cP at 400° F.
 18. The method of claim 16 wherein the hard PENasphalt is blended into the asphalt base, wherein the hard PEN asphalthas a softening point which is within the range of 140° F. to 240° F.,wherein the hard PEN asphalt has a penetration value which is within therange of 0.5 dmm to 15 dmm at 77° F., and wherein the hard PEN asphalthas a rotational viscosity which is within the range of 25 cP to 450 cPat 400° F.
 19. The method of claim 16 wherein 20 weight percent to 80weight percent of the hard PEN asphalt is blended into 20 weight percentto 80 weight percent of the base asphalt, wherein the hard PEN asphalthas a penetration value which is within the range of 0.2 dmm to 10 dmmat 77° F., wherein a polymer modifier is further blended into theasphalt base at a level which is within the range of 0.5 weight percentto 12 weight percent, and wherein a wax is further blended into theasphalt base at a level which is within the range of 0.5 weight percentto 5 weight percent.
 20. A polymer modified asphalt composition which iscomprised of the industrial asphalt composition of claim 1 and at leastone aggregate or filler.